专利摘要:
Die Erfindung bezieht sich auf ein Kraftwerk mit einer integrierten Kohlevergasungsanlage (4) mit einer Luftzerlegungsanlage (5), einem Kohlevergaser (6) und einer am Kohlevergaser angeschlossenen Wärmetauscher- und Gasentstaubungsanlage (6, 7) sowie mit einem angeschlossenen Gasturbinen-Dampfkraftwerksteil. Bei einem solchen Kraftwerk soll die Gesamtwirtschaftlichkeit vergrößert werden. Die Erfindung sieht hierzu vor, daß eine Ammoniaksyntheseanlage (12) an die Kohlevergasungsanlage (4) unter Zwischenschaltung einer Gasreinigungsanlage (10) und einer Gaszerlegungsanlage (11) angeschlossen ist. Ein Teil des bei der Ammoniaksynthese anfallenden Abgases ist zusammen mit dem in der Gasreinigungsanlage und in der Gaszerlegungsanlage abgetrennten Gasen und ein Teil des Rohgases der Brennkammer (21) des Gasturbinenkraftwerksteils (1) zuleitbar. Ein erfindungsgemäßes Kraftwerk ist insbesondere für den Einsatz als Grundlastkraftwerk geeignet.
公开号:SU1309919A3
申请号:SU843737248
申请日:1984-05-14
公开日:1987-05-07
发明作者:Мюллер Райнер;Шифферс Ульрих
申请人:Крафтверк Унион Аг (Фирма);
IPC主号:
专利说明:

1309
the torus is removed through gas cleaning device 10. Next, the gas is cleaned in U 11 decomposition of the gas using liquid nitrogen supplied through pipeline (T) 25 of U 5 decomposition of air. In doing so, it is purified from all gases except hydrogen and enriched with nitrogen. The synthesized gas is supplied to U 12 for ammonia synthesis and then fed to the ammonia synthesis reactor (P) 14. The gases leaving the P 14 are cooled in the separator 15. When
one
The invention relates to power engineering, in particular to power stations with gas turbine, steam turbine power units and an integrated coal gasification unit.
The purpose of the invention is the eco-growth. nomiches.
In the drawing is a schematic image; e- to the power station.
The power plant consists of gas turbine 1 and steam turbine 2 power units and installation 3 for the production of chemical raw materials. Installation 3 for the production of chemical products contains an integrated installation for coal gasification 4, which includes an air decomposition installation 5 connected to a gas generator 6 coal, a heat exchanger 7 and a dust removal device 8 from a gas. In addition, unit 3 for the production of chemical raw materials includes a conversion unit 9, a gas cleaning device 10 and a gas decomposition unit 11, to which an ammonia synthesis unit 12 is attached. The latter contains a gas compressor 13, an ammonia synthesis reactor 14; ammonia chiller and gas separator 15, as well as recirculation pipe 16 for non-transformed synthesis gas with an intermediately activated compressor. 7
Gas turbine power unit 1 is equipped with a gas turbine 18, which drives a compressor 19 and a generator 20. To a gas turbine 18
nineteen
ammonia is released as condensate. Exhaust gases through T 16 are vented to P 14. Part of the gas stream with non-substituted components is withdrawn to T 22, where it is biased with residual gases U 11 and device 10, after which their mixture is compressed in the combustion chamber 21 turbines 18. When using coal with a high content of sulfur, gas washing U 23 is recommended to be used in T 22. 4 3.p. f-ly, 1 ill.
five
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connected to the combustion chamber 21, connected on one side through the pipeline 22 of combustible gas to the installation 3 for the production of chemical raw materials with combustible gas, and on the other hand to the compressor 19. The pipeline 22 of combustible gas is connected through a cleaning device, made in the form of gas washing installation 23, to the crude gas pipeline 24 connecting the coal gasification unit 4 with the conversion unit 9, as well as to the pipelines 25 of the air decomposition unit 5, which also has oxygen removal lines 26 into the gas a generator 6. A waste heat boiler 28 is connected to the waste gas line of the gas turbine 18 28. The waste heat boiler 29 is connected to the steam turbine 30 of the steam turbine power unit 3, the steam turbine 30 consists of
31 high pressure (CWD) and parts
32 low pressure (PND). It is connected to the generator 33. After the PND 32, the capacitor 34, the condenser pump 35, the feed water tank 36 and the feed water pumps 37 and 38 are installed in series.
The power plant works as follows.
The gas generator 6 is supplied with coal and oxygen through line 26 from the connected air decomposition unit 5. In addition, process steam is introduced into the gas generator 6 coal. Coal.gasses with oxygen and process steam in
3, 130991
Clean gas containing carbon monoxide and hydrogen. This crude gas is cooled in a heat exchanger 7 connected to a gas generator 6 coal. The heat released in the heat exchanger 7 is used to produce steam. Then, the unpurified gas is released in the dust removal device 8 from the gas supplied to it by water from dust particles that are in it. Depending on the mode of operation of the power plants, the crude gas subjected to such purification may be supplied to different parts of the combustion chamber 21 of the gas-turbine I8 and the subsequent conversion steps in unit 3 for the production of chemical raw materials.
20
From installation 4 gasification neo-,
Primary gas is primarily carried out through a conversion unit 9. In it carbon monoxide contained in the crude gas, with the help of water pre-25, is formed into hydrogen and carbon dioxide. Carbon dioxide and the hydrogen sulfide contained in it are removed in a sequentially connected gas cleaning device 10 according to a known method. The gas thus purified, containing essentially only hydrogen and, depending on the degree of conversion of carbon monoxide to a more or less severe degree, is cleaned in the decomposition unit 11 using the liquid nitrogen supplied from the decomposition unit 5 via the pipeline 25 from all other gases with the exception of hydrogen, and at the same time g is also enriched with nitrogen. At the same time, at the outlet of the plant 1 1 is decomposed-, the NIN of the gas must be set to a 3: 1 ratio of hydrogen to nitrogen. This synthesis gas is supplied to plant 12 for ammonia synthesis. There, it is first of all compressed with gas-i compressor 13 to process pressure and then introduced into ammonia synthesis reactor 14. Gases leaving ammonia synthesis reactor n 14 and incompletely converted containing ammonia are cooled in a sequentially connected gas separator 15. In this case, ammonia is discharged as condensate. The flue gases through the recirculation pipe 16 are discharged to the ammonia synthesis reactor 14. Part of the reduced waste gases
94
as a so-called cleaning gas with non-substituted gas components, 22 combustible gases are diverted into the pipeline and, together with the crude gas, are combusted in the combustion chamber 21 of the gas turbine 18. The residual gases of the gas decomposition unit I1 and the gas cleaning device 10 are discharged The vehicle is in the pipeline 22 of combustible gas and is combusted with the raw gas. The combustible waste gases of the gas turbine 18 are conducted through the waste heat boiler 28 and give up most of their heat there. In the boiler 28, fresh steam is generated from the water supplied by the feedwater pump 37. This steam, together with the steam supplied to the heat exchanger 7, is supplied to the steam turbine 30. From the respective steps of the parts pressure. Steam turbine 30 is used to extract process steam, which is necessary for the operation of the gas generator 6 coal and for various conversion stages. The steam used in the steam turbine 30 is condensed in the condenser 34 and supplied as a feed water through a condensate pump 35 to the feed water tank 36.
When using coal with a high content of sulfur, it is recommended to install the gas-washing unit 23 into the combustible gas pipeline 22 leading from the dust removal device 8 to the gas turbine combustion chamber 2 in order not to exceed the allowable amount of sulfur emissions in the gas turbine 18. For this, it is sufficiently simple to install, by means of which hydrogen sulfide is diluted using a suitable solvent.
When using coal with significant sulfur content, it may also be advantageous to supply cooled raw gas leaving the dust removal devices 8 from the gas, partially bypassing the conversion unit 9 of the gas cleaning unit 10 and decomposing the unit II nor gas. As a consequence, gas decomposition unit 11 produces substantially more carbon monoxide and less hydrogen. Thereby, more of the carbonaceous gas containing carbon monoxide can be supplied to the combustion chamber 21. For this in installation 12 for syn5130991
Theme ammonia is less synthesized gas.
权利要求:
Claims (5)
[1]
1. Power stations with gas turbine and steam turbine power units, the first of which is equipped with a combustion chamber and a gas turbine, and the second is connected to the exhaust gas turbine through a heating medium, an integrated coal gasifier, a gas generator, an oxygen removal unit and an air decomposition unit with oxygen extraction pipelines in the gas generator and nitrogen, connected at the entrance through the gas pipeline to the gasification installation, the synthesis reactor from the components of the generated pelvis, and at the exit through the gas rovoda - a combustion chamber of a gas turbine unit and the cleaning device, characterized in that, for the purpose audio povshe- efficiency, power plant provided with an additional cleaning device, and gas decomposition installation in series in the gas pipeline between the gas supply installation
Compiled by A. Bulynko Editor N. Lazarenko- Techred M. Hsdanich
Korrek Signature
1809/58 Circulation 482
VNYIPI USSR State Committee. for inventions and discoveries 113035, Moscow, Zh-35, Raushsk nab., 4/5
. Production and printing company, Uzhgorod, Projecto st., 4
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and a synthesis reactor, the latter being in the form of an ammonia synthesis plant, and an additional cleaning device and a decomposition unit. gas at the outlet is connected to a gas pipeline at the entrance to the combustion chamber of the gas turbine power unit.
[2]
2. The power plant according to claim 1, characterized in that the installation of: - gas decomposition is connected to the nitrogen exhaust line of the air decomposition plant.
[3]
3. The power plant in accordance with claim 2, that is, that the nitrogen withdrawal line of the air decomposition plant is connected to the gas pipeline at the entrance to the combustion chamber of the gas turbine power unit.
[4]
4. The power plant according to claim 1, characterized in that a conversion installation is additionally installed in the gas pipeline between the gasification unit and the gas purification unit. .
[5]
5. Power plants on PP. 1-4, about the fact that the device is: - the cleaning device is made in the form of a gas-washing unit for hydrogen sulfide.
Proofreader L.Pilipenko Subscription
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法律状态:
优先权:
申请号 | 申请日 | 专利标题
DE19833320228|DE3320228A1|1983-06-03|1983-06-03|POWER PLANT WITH AN INTEGRATED COAL GASIFICATION PLANT|
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